Show simple item record

dc.contributor.authorGuselnikova O.
dc.contributor.authorMarque S.
dc.contributor.authorTretyakov E.
dc.contributor.authorMareš D.
dc.contributor.authorJeřábek V.
dc.contributor.authorAudran G.
dc.contributor.authorJoly J.-P.
dc.contributor.authorTrusova M.
dc.contributor.authorSvorcik V.
dc.contributor.authorLyutakov O.
dc.contributor.authorPostnikov P.
dc.date.accessioned2020-03-19T19:16:56Z
dc.date.available2020-03-19T19:16:56Z
dc.date.issued2019
dc.identifierV3S-330907
dc.identifier.citationGUSELNIKOVA, O., et al. Unprecedented Plasmon-Induced Nitroxide-Mediated Polymerization (PI-NMP): a Method for Preparation of Functional Surfaces. Journal of Materials Chemistry A. 2019, 7(20), 12414-12419. ISSN 2050-7488. DOI 10.1039/c9ta01630a.
dc.identifier.issn2050-7488 (print)
dc.identifier.issn2050-7496 (online)
dc.identifier.urihttp://hdl.handle.net/10467/87137
dc.description.abstractA plasmon as a stimulus opens up new opportunities for selective and regulated “from-surface” polymerization and functionalization of surfaces. Here, the first example of plasmon-assisted nitroxide-mediated polymerization (NMP) of stimuli-responsive block copolymers poly(N-isopropylacrylamide)-co-4‐vinylboronic acid is reported. The growth of polymer film at room temperature was achieved via plasmon-induced homolysis of alkoxyamines covalently attached to the surface of plasmon-active gold gratings at room temperature. Control of temperature, finite-difference time-domain method simulation of plasmon intensity distribution shift during polymerization, electron paramagnetic resonance experiments, and other assays provide strong support for the plasmon-initiated mechanism of NMP. We demonstrated not only the control of resulting polymer thickness but also the preparation of a SERS chip for detection of glycoproteins as a powerful example of plasmon-assisted NMP potential.eng
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofJournal of Materials Chemistry A
dc.subjectplasmoneng
dc.subjectNMPeng
dc.subjectSERSeng
dc.subjectpolymerizationeng
dc.subjectgratingeng
dc.titleUnprecedented Plasmon-Induced Nitroxide-Mediated Polymerization (PI-NMP): a Method for Preparation of Functional Surfaceseng
dc.typečlánek v časopisecze
dc.typearticleeng
dc.identifier.doihttps://doi.org/10.1039/c9ta01630a
dc.rights.accessclosedAccess
dc.identifier.wos000472219400057
dc.type.statusPeer-reviewed
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-85065961412


Files in this item


This item appears in the following Collection(s)

Show simple item record