dc.contributor.author | Guselnikova O. | |
dc.contributor.author | Marque S. | |
dc.contributor.author | Tretyakov E. | |
dc.contributor.author | Mareš D. | |
dc.contributor.author | Jeřábek V. | |
dc.contributor.author | Audran G. | |
dc.contributor.author | Joly J.-P. | |
dc.contributor.author | Trusova M. | |
dc.contributor.author | Svorcik V. | |
dc.contributor.author | Lyutakov O. | |
dc.contributor.author | Postnikov P. | |
dc.date.accessioned | 2020-03-19T19:16:56Z | |
dc.date.available | 2020-03-19T19:16:56Z | |
dc.date.issued | 2019 | |
dc.identifier | V3S-330907 | |
dc.identifier.citation | GUSELNIKOVA, O., et al. Unprecedented Plasmon-Induced Nitroxide-Mediated Polymerization (PI-NMP): a Method for Preparation of Functional Surfaces. Journal of Materials Chemistry A. 2019, 7(20), 12414-12419. ISSN 2050-7488. DOI 10.1039/c9ta01630a. | |
dc.identifier.issn | 2050-7488 (print) | |
dc.identifier.issn | 2050-7496 (online) | |
dc.identifier.uri | http://hdl.handle.net/10467/87137 | |
dc.description.abstract | A plasmon as a stimulus opens up new opportunities for selective and regulated “from-surface” polymerization and functionalization of surfaces. Here, the first example of plasmon-assisted nitroxide-mediated polymerization (NMP) of stimuli-responsive block copolymers poly(N-isopropylacrylamide)-co-4‐vinylboronic acid is reported. The growth of polymer film at room temperature was achieved via plasmon-induced homolysis of alkoxyamines covalently attached to the surface of plasmon-active gold gratings at room temperature. Control of temperature, finite-difference time-domain method simulation of plasmon intensity distribution shift during polymerization, electron paramagnetic resonance experiments, and other assays provide strong support for the plasmon-initiated mechanism of NMP. We demonstrated not only the control of resulting polymer thickness but also the preparation of a SERS chip for detection of glycoproteins as a powerful example of plasmon-assisted NMP potential. | eng |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.relation.ispartof | Journal of Materials Chemistry A | |
dc.subject | plasmon | eng |
dc.subject | NMP | eng |
dc.subject | SERS | eng |
dc.subject | polymerization | eng |
dc.subject | grating | eng |
dc.title | Unprecedented Plasmon-Induced Nitroxide-Mediated Polymerization (PI-NMP): a Method for Preparation of Functional Surfaces | eng |
dc.type | článek v časopise | cze |
dc.type | journal article | eng |
dc.identifier.doi | 10.1039/c9ta01630a | |
dc.rights.access | closedAccess | |
dc.identifier.wos | 000472219400057 | |
dc.type.status | Peer-reviewed | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85065961412 | |